Volume 26, Issue 6
Heterocyclic Compounds
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ChemInform Abstract: Reactions of 9-Phenylthioxanthene-10-oxide with Organometallic Reagents.

H. SHIMIZU

H. SHIMIZU

Gifu Pharm. Univ., Gifu 502, Japan

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T. KATAOKA

T. KATAOKA

Gifu Pharm. Univ., Gifu 502, Japan

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M. HORI

M. HORI

Gifu Pharm. Univ., Gifu 502, Japan

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First published: February 7, 1995

Abstract

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ChemInform Abstract

The thioxanthene-oxide (I) is converted into the alkylated thioxanthene (III) on treatment with the grignard compounds (II). The reduced derivatives (IV) are formed as by-products. The observation, that the side-products (V) and (VI) are generated, leads to the proposition of a mechanism.

chemical structure image

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