Volume 25, Issue 35
Heterocyclic Compounds
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ChemInform Abstract: Pd-Catalyzed Intramolecular Coupling Between Tertiary Amines and Allylic Groups; Synthesis of 3-Hydro-1H-2-benzazepinium Salts.

M. GRELLIER

M. GRELLIER

Lab. Synth. Met.-induites, CNRS, Univ. Louis Pasteur, F-67070 Strasbourg, Fr.

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M. PFEFFER

M. PFEFFER

Lab. Synth. Met.-induites, CNRS, Univ. Louis Pasteur, F-67070 Strasbourg, Fr.

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G. VAN KOTEN

G. VAN KOTEN

Lab. Synth. Met.-induites, CNRS, Univ. Louis Pasteur, F-67070 Strasbourg, Fr.

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First published: August 30, 1994

Abstract

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ChemInform Abstract

The Pd(0)-catalyzed intramolecular coupling reaction of benzylic amines yields either the desired 2-benzazepinium salts (II) (required for pharmacological studies) benzopyrrolium derivatives depending on the substitution pattern of the double bond.

chemical structure image

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