Volume 25, Issue 35
Preparative Organic Chemistry
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ChemInform Abstract: Asymmetric Cyclopropanation Catalyzed by Chiral Cobalt(II) Complexes from (1R)-3-Hydroxymethylenebornane-2-thione.

G. JOMMI

G. JOMMI

Dip. Chim. Org. Ind., Univ. Stud., 20133 Milano, Italy

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R. PAGLIARIN

R. PAGLIARIN

Dip. Chim. Org. Ind., Univ. Stud., 20133 Milano, Italy

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G. RIZZI

G. RIZZI

Dip. Chim. Org. Ind., Univ. Stud., 20133 Milano, Italy

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M. SISTI

M. SISTI

Dip. Chim. Org. Ind., Univ. Stud., 20133 Milano, Italy

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First published: August 30, 1994

Abstract

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ChemInform Abstract

The cyclopropanation of the olefins (I) with ethyl diazoacetate (II) catalyzed by a chiral cobalt complex leads to the formation of (III) and (IV).

chemical structure image

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