Volume 25, Issue 13
Preparative Organic Chemistry
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ChemInform Abstract: Synthesis of α,α-Difluoro Nitriles from Acyl Cyanides.

E. BARTMANN

E. BARTMANN

E. Merck, Ind. Chem. Div., Dep. Liquid Crystal Res., 64293 Darmstadt, Germany

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J. KRAUSE

J. KRAUSE

E. Merck, Ind. Chem. Div., Dep. Liquid Crystal Res., 64293 Darmstadt, Germany

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First published: March 29, 1994

Abstract

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ChemInform Abstract

Reaction of the aroyl cyanides (III) with diethylaminosulfur trifluoride (DAST) yields the aromatic α,α-difluoro nitriles (IV) which are of interest because of their liquid crystalline properties.

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