Preparative Organic Chemistry
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ChemInform Abstract: Hydroalumination of Alkynes with LiAlH4-CH3OH Catalyzed by Cp2TiCl2.
First published: March 29, 1994
Abstract
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ChemInform Abstract
TiCl2(Cp)2-catalyzed hydroalumination of alkynes using the LiAlH4-MeOH reagent system affords selectively the monohydroaluminated products in good yields under mild experimental conditions. A slight preference of cis-addition is observed in the hydroalumination of internal alkynes.
