Volume 25, Issue 13
Physical Organic Chemistry
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ChemInform Abstract: X-Ray Analysis of a Captodative Diphosphene, 1-(N-Mesityl-9- fluorenylamino)-2-(2,4,6-tris(trifluoromethyl)phenyl)diphosphene.

M. YOSHIFUJI

M. YOSHIFUJI

Dep. Chem., Fac. Sci., Tohoku Univ., Aoba, Sendai 980, Japan

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M. ABE

M. ABE

Dep. Chem., Fac. Sci., Tohoku Univ., Aoba, Sendai 980, Japan

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K. TOYOTA

K. TOYOTA

Dep. Chem., Fac. Sci., Tohoku Univ., Aoba, Sendai 980, Japan

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I. MIYAHARA

I. MIYAHARA

Dep. Chem., Fac. Sci., Tohoku Univ., Aoba, Sendai 980, Japan

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K. HIROTSU

K. HIROTSU

Dep. Chem., Fac. Sci., Tohoku Univ., Aoba, Sendai 980, Japan

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First published: March 29, 1994

Abstract

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ChemInform Abstract

The effect of the N-substituents of title compound (I) for the stabilization of low coordinative organo-phosphorus compounds is discussed by means of X-ray data. The MO calculation of (II) as a captodative push-pull model compound is reported.

chemical structure image

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