ChemInform Abstract: Synthesis and Characterization of the Monomeric Digallylphosphane and Digallylarsane Derivatives MesP(Ga(Trip)2)2×Et2O and PhAs(Ga( Trip)2)2.
Abstract
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ChemInform Abstract
The title compounds (III) represent the first examples of monomeric digallylphosphanes and -arsanes structurally characterized by X-ray analysis and variable-temp. 1H and 31P NMR spectra. (IIIa) crystallizes in the space group P21/c with Z = 4 and (IIIb) in P1 with Z = 2.