Volume 24, Issue 32
Organoelement Compounds
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ChemInform Abstract: The Reaction of Norbornene with Selenium(II) and Selenium(IV) Fluorides.

S. A. LERMONTOV

S. A. LERMONTOV

Inst. Phys. Active Comp., Russian Acad. Sci., 142432 Chernogolovka, Moscow Region, Russia

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S. I. ZAVORIN

S. I. ZAVORIN

Inst. Phys. Active Comp., Russian Acad. Sci., 142432 Chernogolovka, Moscow Region, Russia

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A. N. PUSHIN

A. N. PUSHIN

Inst. Phys. Active Comp., Russian Acad. Sci., 142432 Chernogolovka, Moscow Region, Russia

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A. N. CHEKHLOV

A. N. CHEKHLOV

Inst. Phys. Active Comp., Russian Acad. Sci., 142432 Chernogolovka, Moscow Region, Russia

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N. S. ZEFIROV

N. S. ZEFIROV

Inst. Phys. Active Comp., Russian Acad. Sci., 142432 Chernogolovka, Moscow Region, Russia

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P. J. STANG

P. J. STANG

Inst. Phys. Active Comp., Russian Acad. Sci., 142432 Chernogolovka, Moscow Region, Russia

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First published: August 10, 1993

Abstract

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ChemInform Abstract

When norbornene (I) is treated with phenylselenenyl fluoride (II), mainly the trans-addition products (III) and (IV) are detected. Otherwise, when the trifluoride (V) is used instead of (II), only the cis-exo-addition product (VI) and the Wagner-Meerwein rearrangement product (VII) are obtained after reduction.

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