ChemInform Abstract: The Reaction of Norbornene with Selenium(II) and Selenium(IV) Fluorides.
Abstract
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ChemInform Abstract
When norbornene (I) is treated with phenylselenenyl fluoride (II), mainly the trans-addition products (III) and (IV) are detected. Otherwise, when the trifluoride (V) is used instead of (II), only the cis-exo-addition product (VI) and the Wagner-Meerwein rearrangement product (VII) are obtained after reduction.