ChemInform Abstract: A Versatile and Highly Stereocontrolled Synthetic Approach to Homochiral Polyfunctional Norbornene and Norbornane Derivatives.
Abstract
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ChemInform Abstract
A series of important homochiral building blocks such as (III) and (IV) is prepared starting from the D-mannitol derivative (I) as the unique chiral precursor. The stereochemistry of the products is assured by controlling the facial and endo/exo diastereoselectivity in Diels- Alder reactions.