ChemInform Abstract: Addition of Alkynes to (Vinylketene)tricarbonyliron(0) Complexes.

K. G. MORRIS,

K. G. MORRIS

Dep. Chem., Imperial Coll. Sci., Technol. Med., South Kensington, London SW7 2AY, UK

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S. P. SABERI,

S. P. SABERI

Dep. Chem., Imperial Coll. Sci., Technol. Med., South Kensington, London SW7 2AY, UK

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A. M. Z. SLAWIN,

A. M. Z. SLAWIN

Dep. Chem., Imperial Coll. Sci., Technol. Med., South Kensington, London SW7 2AY, UK

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S. E. THOMAS,

S. E. THOMAS

Dep. Chem., Imperial Coll. Sci., Technol. Med., South Kensington, London SW7 2AY, UK

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D. J. WILLIAMS,

D. J. WILLIAMS

Dep. Chem., Imperial Coll. Sci., Technol. Med., South Kensington, London SW7 2AY, UK

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K. G. MORRIS,

K. G. MORRIS

Dep. Chem., Imperial Coll. Sci., Technol. Med., South Kensington, London SW7 2AY, UK

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S. P. SABERI,

S. P. SABERI

Dep. Chem., Imperial Coll. Sci., Technol. Med., South Kensington, London SW7 2AY, UK

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A. M. Z. SLAWIN,

A. M. Z. SLAWIN

Dep. Chem., Imperial Coll. Sci., Technol. Med., South Kensington, London SW7 2AY, UK

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S. E. THOMAS,

S. E. THOMAS

Dep. Chem., Imperial Coll. Sci., Technol. Med., South Kensington, London SW7 2AY, UK

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D. J. WILLIAMS,

D. J. WILLIAMS

Dep. Chem., Imperial Coll. Sci., Technol. Med., South Kensington, London SW7 2AY, UK

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First published: April 6, 1993

https://doi.org/10.1002/chin.199314245

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Abstract

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ChemInform Abstract

High regioselectivities are observed in the addition reaction of the alkynes (II) with the title complexes (I) to give either the products ( III) or (IV) (X-ray analysis of (IIIa) and (IVc)).