ChemInform Abstract: Electrosynthesis of Amino Acids from a Molybdenum Nitride via Nitrogen- Carbon and Carbon-Carbon Bond Formation Reactions Involving Imides and Nitrogen Ylides: X-Ray Structure of trans-(MoCl(NCHCO2Me)( Ph2PCH2CH2PPh2)2)×CH2Cl2.
Abstract
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ChemInform Abstract
Amino acid estes such as (V) are synthesized from the molybdenum nitride (I) via formation of imide and nitrogen ylide intermediates and an electrochemical Mo-N bond cleavage step. A single crystal X-ray structure of the nitrogen ylide (III) is carried out (space group C2; Z = 4). The use of asymmetric tertiary phosphine co-ligands might allow access to optically active products.
