Preparative Organic Chemistry
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ChemInform Abstract: Laser Flash Photolysis Studies on 4-Oxocyclohexa-2,5-dienylidenes.
First published: April 6, 1993
Abstract
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ChemInform Abstract
The laser flash photolysis of the diazocyclohexadienone derivatives (I) gives the corresponding carbenes which react with triplet oxygen to form the carbonyl oxides (II). Further reactions of the carbene derived from (Ia) are the insertion into the O-H bond of methanol (III) or the formation of the ylide (VI) upon treatment with acetonitrile ( V).
