Volume 24, Issue 14
Preparative Organic Chemistry
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ChemInform Abstract: Photochemistry of Dimethyl 3,3-Dimethyl-1,4,5-hexatriene-1,1- dicarboxylate and Its Homologues.

K. SUGIYAMA

K. SUGIYAMA

Dep. Ind. Chem., Coll. Ind. Technol., Nihon Univ., Narashino, Chiba 275, Japan

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T. TSUNO

T. TSUNO

Dep. Ind. Chem., Coll. Ind. Technol., Nihon Univ., Narashino, Chiba 275, Japan

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First published: April 6, 1993

Abstract

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ChemInform Abstract

Both the direct and the acetone-sensitized photolysis of the title compounds (I) and (IV) proceed via a facile intramolecular (2 + 2) cycloaddition leading to corresponding bicyclo(2.1.0)pentanes. Quantum yields are given.

chemical structure image

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