Preparative Inorganic Chemistry
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ChemInform Abstract: Sulfur Compounds. Part 137. Raman, Mass, and 77Se NMR Spectra of SeSCl2 and Its Reactions with Potassium Iodide and Titanocene Pentasulfide to Produce Cyclic Selenium Sulfides.
First published: October 1, 1991
Abstract
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ChemInform Abstract
The title compound SeSCl2 is obtained from the reaction of a mixture of S2Cl2 and Se2Cl2 at 21 °C. This species reacts with titanocene pentasulfide as well as with KI to give a variety of cyclic selenium sulfides. SCl2 and Se2Cl2 react quantitatively to yield SeCl4 and S2Cl2.
