Volume 22, Issue 39
Physical Inorganic Chemistry
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ChemInform Abstract: MS Xα Studies on the Colors of BiPh5, PbCl2- 6, and WS2- 4: Are Relativistic Effects on the LUMO Important?

B. D. EL-ISSA

B. D. EL-ISSA

Dep. Chem., Univ. Helsinki, 00100 Helsinki, Finland

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P. PYYKKOE

P. PYYKKOE

Dep. Chem., Univ. Helsinki, 00100 Helsinki, Finland

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H. M. ZANATI

H. M. ZANATI

Dep. Chem., Univ. Helsinki, 00100 Helsinki, Finland

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First published: October 1, 1991

Abstract

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ChemInform Abstract

The violet color of BiPh5 and the yellow color of PbCl2- 6 are attributed to the relativistic stabilization of an a1* LUMO. The color difference between MoS2- 4 and WS2- 4 is mainly due to the shell- structure effects.

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