ChemInform Abstract: Synthesis and Reactivity of 3-Thia-7,7-dimethyl-7-germabicyclo(3.3.0)oct-1(5)-ene and Its Selenium Analog.
Abstract
ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option.
ChemInform Abstract
The selena-germabicyclooctene (IIIb) on reaction with DDQ gives the expected selenophene derivative. The nature of compounds formed in the oxidation of (IIIa) with m-chloroperbenzoic acid depends on the experimental conditions. If (IIIa) is reacted wtih MCPBA in equimolecular amounts in Et2O at 0 °C, the expected sulfoxide (V) is formed together with some sulfone (VI).
