ChemInform Abstract: Asymmetric Addition of Ethyl Azidoformate to Optically Active Enamines. Reversal of Facial Selectivity Compared with (Ethoxycarbonyl)nitrene.
Abstract
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ChemInform Abstract
When ethoxycarbonylnitrene is used for the addition to the enamines (I) the enantiomer (R)-(III) is formed.