Volume 22, Issue 16
Isocyclic Compounds
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ChemInform Abstract: Asymmetric Addition of Ethyl Azidoformate to Optically Active Enamines. Reversal of Facial Selectivity Compared with (Ethoxycarbonyl)nitrene.

S. FIORAVANTI

S. FIORAVANTI

Dip. Chim., Univ. “La Sapienza”, I-00185 Roma, Italy

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M. A. LORETO

M. A. LORETO

Dip. Chim., Univ. “La Sapienza”, I-00185 Roma, Italy

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L. PELLACANI

L. PELLACANI

Dip. Chim., Univ. “La Sapienza”, I-00185 Roma, Italy

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P. A. TARDELLA

P. A. TARDELLA

Dip. Chim., Univ. “La Sapienza”, I-00185 Roma, Italy

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First published: April 23, 1991

Abstract

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ChemInform Abstract

When ethoxycarbonylnitrene is used for the addition to the enamines (I) the enantiomer (R)-(III) is formed.

chemical structure image

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