Organoelement Compounds

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ChemInform Abstract: Oxidatively Induced Reductive Elimination. A Novel Titanium Complex Resulting from C-F Bond Activation.

M. J. BURK,

M. J. BURK

Central Res. Dev., E. I. du Pont de Nemours Co., Inc., Exper. Station, Wilmington, DE 19880, USA

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D. L. STALEY,

D. L. STALEY

Central Res. Dev., E. I. du Pont de Nemours Co., Inc., Exper. Station, Wilmington, DE 19880, USA

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W. TUMAS,

W. TUMAS

Central Res. Dev., E. I. du Pont de Nemours Co., Inc., Exper. Station, Wilmington, DE 19880, USA

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M. J. BURK,

M. J. BURK

Central Res. Dev., E. I. du Pont de Nemours Co., Inc., Exper. Station, Wilmington, DE 19880, USA

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D. L. STALEY,

D. L. STALEY

Central Res. Dev., E. I. du Pont de Nemours Co., Inc., Exper. Station, Wilmington, DE 19880, USA

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W. TUMAS,

W. TUMAS

Central Res. Dev., E. I. du Pont de Nemours Co., Inc., Exper. Station, Wilmington, DE 19880, USA

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First published: November 27, 1990

https://doi.org/10.1002/chin.199048233

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Abstract

The titanacyclobutanes (I) react with tetrakis(trifluoromethyl)cyclopentadienone (II) in dichloromethane to produce the titanium complex (III).