Organoelement Compounds
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ChemInform Abstract: The iso-Tetraphosphane P(P(SiMe3)(C6H5))3.
First published: November 27, 1990
Abstract
The preparation of the title compound (III) from PCl3 (I) and the Li phosphide (II) requires two steps: at -78 °C PCl3 (I) reacts with two equiv. (II) without side reactions; at -35 °C the formed intermediate (Ph(Tms)P)2PCl reacts with the third phosphide (II) to yield (III) quite cleanly.
ChemInform Abstract
The preparation of the title compound (III) from PCl3 (I) and the Li phosphide (II) requires two steps: at -78 °C PCl3 (I) reacts with two equiv. (II) without side reactions; at -35 °C the formed intermediate (Ph(Tms)P)2PCl reacts with the third phosphide (II) to yield (III) quite cleanly. The results of a NMR investigation of (III) are reported.
