Volume 21, Issue 37
Natural Products
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ChemInform Abstract: D-3,4-′Cyclopropylglutamate′ Isomers as NMDA Receptor Ligands: Synthesis and Enantioselective Activity.

R. PELLICCIARI

R. PELLICCIARI

Ist. Chim. Farm. Techn. Farm., Univ. Stud., Perugia, Italy

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B. NATALINI

B. NATALINI

Ist. Chim. Farm. Techn. Farm., Univ. Stud., Perugia, Italy

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M. MARINOZZI

M. MARINOZZI

Ist. Chim. Farm. Techn. Farm., Univ. Stud., Perugia, Italy

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J. B. MONAHAN

J. B. MONAHAN

Ist. Chim. Farm. Techn. Farm., Univ. Stud., Perugia, Italy

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First published: September 11, 1990

ChemInform Abstract

The N-(benzyloxycarbonyl)-D-vinylglycine methyl ester (I) reacts with the diazoacetate (II) under rhodium-catalyzed thermolysis to give a mixture of 4 cyclopropane derivatives, the separation procedures of which are described in the original paper as well as the assignments of their absolute configurations.

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