Volume 21, Issue 37
Organoelement Compounds
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ChemInform Abstract: Reactive E=C(p-p) π-Systems. Part 24. A Novel Coordination Mode of Acyclic Phosphaalkenes: F3CP=C(F)NMe2 as a (η1-μ2) 4e Donor.

J. GROBE

J. GROBE

Anorg.-Chem. Inst., Westfael. Wilhelms-Univ. Muenster, D-4400 Muenster

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D. LE VAN

D. LE VAN

Anorg.-Chem. Inst., Westfael. Wilhelms-Univ. Muenster, D-4400 Muenster

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B. KREBS

B. KREBS

Anorg.-Chem. Inst., Westfael. Wilhelms-Univ. Muenster, D-4400 Muenster

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R. + FROEHLICH

R. + FROEHLICH

Anorg.-Chem. Inst., Westfael. Wilhelms-Univ. Muenster, D-4400 Muenster

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A. SCHIEMANN

A. SCHIEMANN

Anorg.-Chem. Inst., Westfael. Wilhelms-Univ. Muenster, D-4400 Muenster

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First published: September 11, 1990

Abstract

The Cr complex (I) in CHCl3 solution slowly decomposes with elimination of the free ligand (III) to give the binuclear complex (II) (space group P21/n, Z=4).

ChemInform Abstract

The Cr complex (I) in CHCl3 solution slowly decomposes with elimination of the free ligand (III) to give the binuclear complex (II) (space group P21/n, Z=4). Its X-ray structure analysis reveals a so far unknown coordination mode of acyclic phosphaalkenes.

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