ChemInform Abstract: Reactive E=C(p-p) π-Systems. Part 24. A Novel Coordination Mode of Acyclic Phosphaalkenes: F3CP=C(F)NMe2 as a (η1-μ2) 4e Donor.
Abstract
The Cr complex (I) in CHCl3 solution slowly decomposes with elimination of the free ligand (III) to give the binuclear complex (II) (space group P21/n, Z=4).
ChemInform Abstract
The Cr complex (I) in CHCl3 solution slowly decomposes with elimination of the free ligand (III) to give the binuclear complex (II) (space group P21/n, Z=4). Its X-ray structure analysis reveals a so far unknown coordination mode of acyclic phosphaalkenes.