Organoelement Compounds
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ChemInform Abstract: Intramolecular Amine Coordination versus NMe C-H Activation: The Stereoselective Synthesis of a Tantala(V)azacyclopropane Complex.
First published: September 11, 1990
Abstract
A stereoselective C-H activation reaction of a NMe group of the Ta(V) compound (I) affords toluene and the new pentagonal pyramidal Ta(V) THF adduct (III) (space group P1, Z=4).
ChemInform Abstract
A stereoselective C-H activation reaction of a NMe group of the Ta(V) compound (I) affords toluene and the new pentagonal pyramidal Ta(V) THF adduct (III) (space group P1, Z=4). The chirality of the arylamine leads to a single structurally characterized diastereoisomer in which intramolecular coordination of the modified amine group produces a triangular cyclic Ta-CH2-N unit.
