Volume 21, Issue 37
Preparative Organic Chemistry
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ChemInform Abstract: 1,3-Dipolar Cycloadditions of 2-Ethoxy- and 2-(Ethylthio)-1-azetines with Nitrile Oxides and Nitrile Ylides.

A.-B. N. LUHESHI

A.-B. N. LUHESHI

Dep. Chem. Appl. Chem., Univ. Salford, Salford, Manchester M5 4WT, UK

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R. K. SMALLEY

R. K. SMALLEY

Dep. Chem. Appl. Chem., Univ. Salford, Salford, Manchester M5 4WT, UK

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P. D. KENNEWELL

P. D. KENNEWELL

Dep. Chem. Appl. Chem., Univ. Salford, Salford, Manchester M5 4WT, UK

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R. WESTWOOD

R. WESTWOOD

Dep. Chem. Appl. Chem., Univ. Salford, Salford, Manchester M5 4WT, UK

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First published: September 11, 1990

Abstract

The azetines (I), obtained from the corresponding (thio)lactams in a known manner, react with nitrile oxides generated in situ to give the 1,3-dipolar cycloadducts (III).

ChemInform Abstract

The azetines (I), obtained from the corresponding (thio)lactams in a known manner, react with nitrile oxides generated in situ to give the 1,3-dipolar cycloadducts (III). Further examples are given in the original paper. The analogous reaction between azetines and nitrile sulfides, azomethine ylides, nitrones, or aryl azides is not observed.

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