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ChemInform Abstract: 3-Methylxanthosine: Synthesis and Acidic Hydrolysis of the Glycosyl Bond.
First published: January 2, 1990
Abstract
3-Methylxanthosine (IVb) is prepared by ethoxycarbonylation of the nucleoside (I) and subsequent base-induced cyclization of the carbamate (III).
ChemInform Abstract
3-Methylxanthosine (IVb) is prepared by ethoxycarbonylation of the nucleoside (I) and subsequent base-induced cyclization of the carbamate (III). Acidic hydrolysis of the N-glycosidic bond in (IVb) proceeds about 1000 times faster than in xanthosine (IVa).
