ChemInform Abstract: Synthesis of Two Useful, Enantiomerically Pure Derivatives of (S)-4-Hydroxy-2-cyclohexenone.
Abstract
Oxidation and subsequent dehydration of the triol (I) yield the cyclohexenone (II) which is hydrogenated to give the cyclohexanone (III).
ChemInform Abstract
Oxidation and subsequent dehydration of the triol (I) yield the cyclohexenone (II) which is hydrogenated to give the cyclohexanone (III). From this, the title derivatives (V) and (VII) are prepared via DBU-induced elimination and subsequent protection of the hydroxy group.