Preparative Organic Chemistry
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ChemInform Abstract: Reactivity of Polycyclic Aromatic Aryl Radicals.
First published: May 30, 1989
Abstract
Results of theoretical (MNDO) and experimental studies of the properties and reactions of phenyl, 1- and 2-naphthalenyl, and 9-anthracenyl radicals with toluene and naphthalene (gas phase at 400 and 450 °C) are reported.
ChemInform Abstract
Results of theoretical (MNDO) and experimental studies of the properties and reactions of phenyl, 1- and 2-naphthalenyl, and 9-anthracenyl radicals with toluene and naphthalene (gas phase at 400 and 450 °C) are reported. Arylation rates for each radical are measured relative to hydrogen abstraction from toluene (kar/kabs).
