Organoelement Compounds
Full Access
ChemInform Abstract: Lewis-Base Adducts of Group 11 Metal(I) Compounds. Part 37. A Novel Isomerism in the Heterobimetallic 1:1 Adducts of Copper(I) Halides with Tris(dithiocarbamato)cobalt(III).
First published: January 10, 1989
Abstract
Both adducts (III) are prepared by slow interdiffusion of dilute solutions of the tris(dithiocarbamato)-Co(III) complexes (I) and CuI (II) in acetonitrile and characterized by single-crystal X-ray structure determination ((IIIa): space group P21/c, Z=4; (IIIb): Ccca, Z = 8).
ChemInform Abstract
Both adducts (III) are prepared by slow interdiffusion of dilute solutions of the tris(dithiocarbamato)-Co(III) complexes (I) and CuI (II) in acetonitrile and characterized by single-crystal X-ray structure determination ((IIIa): space group P21/c, Z=4; (IIIb): Ccca, Z = 8). The chiralities of the pair of the Co(III) dithiocarbamate moieties in the dipropyl adduct (IIIa) are opposite, whereas in the isopropyl adduct (IIIb) they are the same.
