Volume 20, Issue 2
Heterocyclic Compounds
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ChemInform Abstract: A Diels-Alder Route Towards Pyrimidin-4-ones.

PH. BAYARD

PH. BAYARD

Lab. Chim. Org. Synth., Univ. Cathol., 1348 Louvain, Belgium

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F. SAINTE

F. SAINTE

Lab. Chim. Org. Synth., Univ. Cathol., 1348 Louvain, Belgium

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R. BEAUDEGNIES

R. BEAUDEGNIES

Lab. Chim. Org. Synth., Univ. Cathol., 1348 Louvain, Belgium

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L. GHOSEZ

L. GHOSEZ

Lab. Chim. Org. Synth., Univ. Cathol., 1348 Louvain, Belgium

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First published: January 10, 1989

Abstract

The iminoether hydrochlorides (I) react with the acetyl chlorides (II) to form the iminoamides (III) which are silylated, yielding the silyl enol ethers (V).

ChemInform Abstract

The iminoether hydrochlorides (I) react with the acetyl chlorides (II) to form the iminoamides (III) which are silylated, yielding the silyl enol ethers (V). These undergo cycloaddition reaction with the nitriles (VI) to produce the pyrimidinones (VII).

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