Volume 20, Issue 2
Isocyclic Compounds
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ChemInform Abstract: Oxidation of 7-Hydroxy-2,6,6-trimethylbicyclo(3.2.0)hept-1-enes.

O. O. VOLKOVA

O. O. VOLKOVA

Vses. nauchno-issled. inst. sint. nat. dushistykh veshchestv., Moskva

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G. V. CHERKAEV

G. V. CHERKAEV

Vses. nauchno-issled. inst. sint. nat. dushistykh veshchestv., Moskva

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M. B. ERMAN

M. B. ERMAN

Vses. nauchno-issled. inst. sint. nat. dushistykh veshchestv., Moskva

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First published: January 10, 1989

Abstract

The title compound (II) is prepared from the acetoxy derivative (I) according to a known procedure.

ChemInform Abstract

The title compound (II) is prepared from the acetoxy derivative (I) according to a known procedure. Oxidation of (II) proceeds via epoxidation of the carbon, carbon double bond and cleavage of the cyclobutane moiety to yield the keto aldehyde (III) instead of the expected bicyclo(3.2.0)diol. A mechanism is discussed.

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