ChemInform Abstract: Hydrido Platinum Metal Macrocyclic Complexes: The Synthesis and Single-Crystal X-Ray Structure of cis-(IrCl(H)L1)PF6 (L1: 7-Methyl-3,7,11,17-tetraazabicyclo(11.3.1)heptadeca-1(17),13,15-triene).

ChemInform Abstract

The title complex (I) is obtained by 1:1 molar reaction of IrCl₃·3H₂O and the macrocycle in refluxing aqueous ethanol followed by addition of NH₄PF₆. Its characterization occurs by elemental analysis, MS, ¹H NMR, and IR spectral data, and X-ray structure analysis (space group P2₁/c, Z=4).