ChemInform Abstract: Cyclooctaselenadiazole: Synthesis, Decomposition Pathway, and Reaction with (η5-C5H5)Co(L)2 (L = C2H4, PPh3). Crystal and Molecular Structure of ((η5-C5H5)Co)2 (μ2-η3,η2-C8H6Se).
Abstract
The cyclooctaselenadiazole (V) is obtained from the known semicarbazone (III) by oxidation with selenium dioxide (IV).
ChemInform Abstract
The cyclooctaselenadiazole (V) is obtained from the known semicarbazone (III) by oxidation with selenium dioxide (IV). Vacuum pyrolysis of (V) yields the compounds (VI) and (VII). The reaction of (V) with cyclopentadiene cobalt complexes is investigated.