Volume 19, Issue 18
Organoelement Compounds
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ChemInform Abstract: Carbamoylation of 2-Aminothiazolines with Diethoxythiophosphoryl Isocyanate.

V. V. NEGREBETSKII

V. V. NEGREBETSKII

VNII khim. sredstv zashchity rastenii, Moskva

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N. N. VOROB'EVA

N. N. VOROB'EVA

VNII khim. sredstv zashchity rastenii, Moskva

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L. V. RAZVODOVSKAYA

L. V. RAZVODOVSKAYA

VNII khim. sredstv zashchity rastenii, Moskva

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A. F. GRAPOV

A. F. GRAPOV

VNII khim. sredstv zashchity rastenii, Moskva

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N. N. MEL'NIKOV

N. N. MEL'NIKOV

VNII khim. sredstv zashchity rastenii, Moskva

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First published: May 3, 1988

Abstract

The 2-alkyl(aryl)aminothiazolines (I) react with the isocyanate (II) at the endocyclic N-atom to give the carbamoylthiazolines (III).

ChemInform Abstract

The 2-alkyl(aryl)aminothiazolines (I) react with the isocyanate (II) at the endocyclic N-atom to give the carbamoylthiazolines (III). In contrast, treatment of 2-aminothiazoline (IV) with (II) takes place at the exocyclic N-atom, producing the carbamoyliminothiazolidine (V) which equilibrates in solution with the tautomeric amino form (VI).

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