Isocyclic Compounds
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ChemInform Abstract: Strong Participation of the 1-Methyl Group in Diazotization Reaction of 9-Aminomethyl-1,4-dimethyltriptycene.
First published: January 26, 1988
Abstract
Diazotization of 9-(aminomethyl)triptycene (Ia) results in methylene insertion to give the bridgehead alcohol derivatives (II).
ChemInform Abstract
Diazotization of 9-(aminomethyl)triptycene (Ia) results in methylene insertion to give the bridgehead alcohol derivatives (II). 1,4-Dimethyl-9-(aminomethyl)triptycene (Ib), prepared from anthracene-9-carboxyaldehyde (III), is diazotized to yield the products (VII) - (X).
