Article
Full Access
ChemInform Abstract: Volumes of Reaction for the Formation of Some Analogues of Tetrahedral Intermediates.
First published: January 26, 1988
Abstract
Both the equilibria shown in the scheme are studied by NMR.
ChemInform Abstract
Both the equilibria shown in the scheme are studied by NMR. Equilibrium constants are measured as a function of pressure (up to 2000 and 1140 bar, respectively) to obtain volumes of reaction which relate to the formation of the "tetrahedral intermediate" of ester hydrolysis. The equilibrium (I)/(II) is studied also as a function of temp. (265-305 K).
