Volume 19, Issue 4
Physical Inorganic Chemistry
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ChemInform Abstract: Structure of MnPO4·H2O by Synchrotron X-Ray Powder Diffraction.

P. LIGHTFOOT

P. LIGHTFOOT

Chem. Crystallogr. Lab., Univ. Oxford, Oxford OX1 3PD, UK

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A. K. CHEETHAM

A. K. CHEETHAM

Chem. Crystallogr. Lab., Univ. Oxford, Oxford OX1 3PD, UK

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A. W. SLEIGHT

A. W. SLEIGHT

Chem. Crystallogr. Lab., Univ. Oxford, Oxford OX1 3PD, UK

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First published: January 26, 1988

Abstract

The quality of refinement that my be obtained from synchrotron X-ray data for a pure, well crystalline phase is demonstrated by determination of the crystal structure of the title compound.

ChemInform Abstract

The quality of refinement that my be obtained from synchrotron X-ray data for a pure, well crystalline phase is demonstrated by determination of the crystal structure of the title compound. MnPO4·H2O crystallizes in the monoclinic system, space group C2/c, Z=4. The structure consists of a network of MnO6 octahedra and PO4 tetrahedra linked together by vertex sharing into a continuous three-dimensional array. trans-Mn-O-Mn chains run parallel to the (101) direction, the oxygen atom of the water molecule being at the vertex of two adjacent MnO6 octahedra.

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