Volume 19, Issue 2
Preparative Organic Chemistry
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ChemInform Abstract: The Evaluation of Dicyclopentadienylsamarium as a Reagent in Organic Synthesis.

J. L. NAMY

J. L. NAMY

Lab. Synth. Asym., UA, CNRS, Univ. Paris-Sud, 91405 Orsay, France

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J. COLLIN

J. COLLIN

Lab. Synth. Asym., UA, CNRS, Univ. Paris-Sud, 91405 Orsay, France

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J. ZHANG

J. ZHANG

Lab. Synth. Asym., UA, CNRS, Univ. Paris-Sud, 91405 Orsay, France

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H. B. KAGAN

H. B. KAGAN

Lab. Synth. Asym., UA, CNRS, Univ. Paris-Sud, 91405 Orsay, France

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First published: January 12, 1988

ChemInform Abstract

Dicyclopentadienylsamarium (III), which is prepared from SmI2 and cyclopentadienylsodium, is used as a reagent for the reductive coupling of the carbonyl compounds (I) with the halides (II), yielding the alcohols (IV).

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