Preparative Organic Chemistry
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ChemInform Abstract: 1,3-Dipoles Are Not the Only Reactive Species in 2-Acylaziridine Pyrolyses.
First published: January 12, 1988
Abstract
The N-(tert-butyl)benzoylaziridines (I) undergo thermolysis to produce the intermediate oxazolines (III) via the dipoles (II).
ChemInform Abstract
The N-(tert-butyl)benzoylaziridines (I) undergo thermolysis to produce the intermediate oxazolines (III) via the dipoles (II). The compounds (III) are trapped with dimethyl acetylenedicarboxylate (IV), yielding the cycloadducts (V) which rearrange to form the pyrrolines (VI).
