Physical Organic Chemistry
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ChemInform Abstract: Cyclic Voltammetry and Resonance Raman Studies of the (Pyridine-2-carbaldoxime)tetracyanoferrate(II) Complex: Evidence of a Nitroso-Oxime Equilibrium.
First published: January 12, 1988
Abstract
Cyclic voltammograms of the complex (I) show that above pH 7 a systematic decrease in the peak currents exists with concomitant growing of a new wave.
ChemInform Abstract
Cyclic voltammograms of the complex (I) show that above pH 7 a systematic decrease in the peak currents exists with concomitant growing of a new wave. This process is completely reversible and can be ascribed to the equilibrium between (I) and (II). The changes in the chromophore group due to the oxime-nitroso conversion are detected by the resonance Raman spectra below pH 7 and at pH 10.
