Volume 18, Issue 38
Natural Products
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ChemInform Abstract: Acylation of Glycofurano(2,1-d)imidazolidine-2-thiones: A Structural Revision.

M. AVALOS GONZALEZ

M. AVALOS GONZALEZ

Dep. Org. Chem., Fac. Sci., Univ. Extremadura, 06071 Badajoz, Spain

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J. L. JIMENEZ REQUEJO

J. L. JIMENEZ REQUEJO

Dep. Org. Chem., Fac. Sci., Univ. Extremadura, 06071 Badajoz, Spain

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J. C. PALACIOS ALBARRAN

J. C. PALACIOS ALBARRAN

Dep. Org. Chem., Fac. Sci., Univ. Extremadura, 06071 Badajoz, Spain

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M. D. RAMOS MONTERO

M. D. RAMOS MONTERO

Dep. Org. Chem., Fac. Sci., Univ. Extremadura, 06071 Badajoz, Spain

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J. A. GALBIS PEREZ

J. A. GALBIS PEREZ

Dep. Org. Chem., Fac. Sci., Univ. Extremadura, 06071 Badajoz, Spain

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First published: September 22, 1987

Abstract

Acetylation of the imidazolidine-2-thiones (I) and (V) leads to the formation of the O-acetylated derivatives (II) and (VI) or the N- and O-acetylated compounds (III) and (VII), depending on the reaction temperature.

ChemInform Abstract

Acetylation of the imidazolidine-2-thiones (I) and (V) leads to the formation of the O-acetylated derivatives (II) and (VI) or the N- and O-acetylated compounds (III) and (VII), depending on the reaction temperature. The position of acetylation is verified spectroscopically and by transformation of (IIIb) and (VIIb) into the corresponding imidazoline-2-ones (IV) and (VIII).

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