ChemInform
Volume 18, Issue 38
Preparative Organic Chemistry
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ChemInform Abstract: Ketonization of 1,3-Cyclohexadienol, a Conjugated Enol.

R. M. POLLACK, 

R. M. POLLACK

Dep. Chem., Univ. Md., Baltimore County, Baltimore, MD 21228, USA

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J. P. G. MACK, 

J. P. G. MACK

Dep. Chem., Univ. Md., Baltimore County, Baltimore, MD 21228, USA

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G. BLOTNY, 

G. BLOTNY

Dep. Chem., Univ. Md., Baltimore County, Baltimore, MD 21228, USA

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First published: September 22, 1987
https://doi.org/10.1002/chin.198738086

ChemInform Abstract

The dienol (Ib), generated in situ from (Ia), ketonizes exclusively to the β,γ-unsaturated isomer (II) (k0 = 1.4·10-2 s-1 in D2O at 25 °C, t1/2 = 48 s).

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