Preparative Organic Chemistry
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ChemInform Abstract: Oxidation of Unsaturated Linear and Cyclic Hydrocarbons with Molecular Oxygen Catalyzed by Transition Metal Complexes.
First published: September 1, 1987
Abstract
The Pd-catalyzed oxidation of the unsaturated hydrocarbons (I), (IV), (VI), and (VIII) gives the ketones (II), (III), (V), (VII), (IX), and (X).
ChemInform Abstract
The Pd-catalyzed oxidation of the unsaturated hydrocarbons (I), (IV), (VI), and (VIII) gives the ketones (II), (III), (V), (VII), (IX), and (X). Under the same conditions, the tetracyclic hydrocarbon (XI) only rearranges, producing the methylene compound (XII) without further oxidation. (IR-, 1H-NMR-data).
