Volume 18, Issue 24
Heterocyclic Compounds
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ChemInform Abstract: Synthesis of Tetrahydrofurans from Active Methylene Compounds via Radical Cyclization.

O. MORIYA

O. MORIYA

Dep. Chem., Natl. Def. Acad., Yokosuka, Kanagawa 239, Japan

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Y. URATA

Y. URATA

Dep. Chem., Natl. Def. Acad., Yokosuka, Kanagawa 239, Japan

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Y. IKEDA

Y. IKEDA

Dep. Chem., Natl. Def. Acad., Yokosuka, Kanagawa 239, Japan

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Y. UENO

Y. UENO

Dep. Chem., Natl. Def. Acad., Yokosuka, Kanagawa 239, Japan

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T. ENDO

T. ENDO

Dep. Chem., Natl. Def. Acad., Yokosuka, Kanagawa 239, Japan

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First published: June 16, 1987

Abstract

The vinyl ethers (III), prepared from the orthoformate (I) and the active methylene compounds (II), are cyclized with tributyltin hydride to yield the tetrahydrofuran derivatives (IV).

ChemInform Abstract

The vinyl ethers (III), prepared from the orthoformate (I) and the active methylene compounds (II), are cyclized with tributyltin hydride to yield the tetrahydrofuran derivatives (IV). (Mechanism, IR-, 1H-NMRdata).

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