Volume 58, Issue 44 p. 15938

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Back Cover: [UF₆]²⁻: A Molecular Hexafluorido Actinide(IV) Complex with Compensating Spin and Orbital Magnetic Moments (Angew. Chem. Int. Ed. 44/2019)

Prof. Dr. Kasper S. Pedersen,

Corresponding Author

Prof. Dr. Kasper S. Pedersen

[email protected]

orcid.org/0000-0002-4381-4544

Univ. Bordeaux, CNRS, Centre de Recherche Paul Pascal, UMR 5031, 33600 Pessac, France

Department of Chemistry, Technical University of Denmark, 2800 Kgs., Lyngby, Denmark

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Dr. Katie R. Meihaus,

Dr. Katie R. Meihaus

orcid.org/0000-0002-5192-863X

Department of Chemistry, University of California, Berkeley, CA, 94720 USA

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Dr. Andrei Rogalev,

Corresponding Author

Dr. Andrei Rogalev

[email protected]

ESRF–The European Synchrotron, 71, Avenue des Martyrs, 38000 Grenoble Cedex 9, France

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Dr. Fabrice Wilhelm,

Dr. Fabrice Wilhelm

ESRF–The European Synchrotron, 71, Avenue des Martyrs, 38000 Grenoble Cedex 9, France

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Dr. Daniel Aravena,

Dr. Daniel Aravena

orcid.org/0000-0003-3140-4852

Departamento de Química de los Materiales, Facultad de Química y Biología, Universidad de Santiago de Chile (USACH), Casilla 40, Correo 33, Santiago, Chile

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Martín Amoza,

Martín Amoza

Departament de Química Inorgànica i Orgànica and Institut de Química Teòrica i Computacional, Universitat de Barcelona, Diagonal 645, 08028 Barcelona, Spain

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Prof. Dr. Eliseo Ruiz,

Prof. Dr. Eliseo Ruiz

orcid.org/0000-0001-9097-8499

Departament de Química Inorgànica i Orgànica and Institut de Química Teòrica i Computacional, Universitat de Barcelona, Diagonal 645, 08028 Barcelona, Spain

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Prof. Dr. Jeffrey R. Long,

Prof. Dr. Jeffrey R. Long

orcid.org/0000-0002-5324-1321

Department of Chemistry, University of California, Berkeley, CA, 94720 USA

Materials Sciences Division, Lawrence Berkeley National Laboratory, Berkeley, CA, 94720 USA

Department of Chemical and Biomolecular Engineering, University of California Berkeley, Berkeley, CA, 94720 USA

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Prof. Dr. Jesper Bendix,

Prof. Dr. Jesper Bendix

orcid.org/0000-0003-1255-2868

Department of Chemistry, University of Copenhagen, 2100 Copenhagen, Denmark

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Dr. Rodolphe Clérac,

Corresponding Author

Dr. Rodolphe Clérac

[email protected]

orcid.org/0000-0001-5429-7418

Univ. Bordeaux, CNRS, Centre de Recherche Paul Pascal, UMR 5031, 33600 Pessac, France

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Prof. Dr. Kasper S. Pedersen,

Corresponding Author

Prof. Dr. Kasper S. Pedersen

[email protected]

orcid.org/0000-0002-4381-4544

Univ. Bordeaux, CNRS, Centre de Recherche Paul Pascal, UMR 5031, 33600 Pessac, France

Department of Chemistry, Technical University of Denmark, 2800 Kgs., Lyngby, Denmark

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Dr. Katie R. Meihaus,

Dr. Katie R. Meihaus

orcid.org/0000-0002-5192-863X

Department of Chemistry, University of California, Berkeley, CA, 94720 USA

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Dr. Andrei Rogalev,

Corresponding Author

Dr. Andrei Rogalev

[email protected]

ESRF–The European Synchrotron, 71, Avenue des Martyrs, 38000 Grenoble Cedex 9, France

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Dr. Fabrice Wilhelm,

Dr. Fabrice Wilhelm

ESRF–The European Synchrotron, 71, Avenue des Martyrs, 38000 Grenoble Cedex 9, France

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Dr. Daniel Aravena,

Dr. Daniel Aravena

orcid.org/0000-0003-3140-4852

Departamento de Química de los Materiales, Facultad de Química y Biología, Universidad de Santiago de Chile (USACH), Casilla 40, Correo 33, Santiago, Chile

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Martín Amoza,

Martín Amoza

Departament de Química Inorgànica i Orgànica and Institut de Química Teòrica i Computacional, Universitat de Barcelona, Diagonal 645, 08028 Barcelona, Spain

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Prof. Dr. Eliseo Ruiz,

Prof. Dr. Eliseo Ruiz

orcid.org/0000-0001-9097-8499

Departament de Química Inorgànica i Orgànica and Institut de Química Teòrica i Computacional, Universitat de Barcelona, Diagonal 645, 08028 Barcelona, Spain

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Prof. Dr. Jeffrey R. Long,

Prof. Dr. Jeffrey R. Long

orcid.org/0000-0002-5324-1321

Department of Chemistry, University of California, Berkeley, CA, 94720 USA

Materials Sciences Division, Lawrence Berkeley National Laboratory, Berkeley, CA, 94720 USA

Department of Chemical and Biomolecular Engineering, University of California Berkeley, Berkeley, CA, 94720 USA

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Prof. Dr. Jesper Bendix,

Prof. Dr. Jesper Bendix

orcid.org/0000-0003-1255-2868

Department of Chemistry, University of Copenhagen, 2100 Copenhagen, Denmark

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Dr. Rodolphe Clérac,

Corresponding Author

Dr. Rodolphe Clérac

[email protected]

orcid.org/0000-0001-5429-7418

Univ. Bordeaux, CNRS, Centre de Recherche Paul Pascal, UMR 5031, 33600 Pessac, France

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First published: 18 September 2019

https://doi.org/10.1002/anie.201911582

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Graphical Abstract

Insights into the electronic properties of actinide ions can be obtained by using X-ray magnetic circular dichroism spectroscopy. In their Communication on page 15650 ff., K. S. Pedersen, R. Clérac, and co-workers present the first structurally characterized hexafluorido complex of a tetravalent actinide ion, [UF₆]^2–. Its non-magnetic ground state results from an almost perfect cancellation of spin and orbital magnetic moments, which are virtually identical in magnitude but opposite in sign.

Volume58, Issue44

October 28, 2019

Page 15938

Back Cover: [UF₆]²⁻: A Molecular Hexafluorido Actinide(IV) Complex with Compensating Spin and Orbital Magnetic Moments (Angew. Chem. Int. Ed. 44/2019)

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Back Cover: [UF6]2−: A Molecular Hexafluorido Actinide(IV) Complex with Compensating Spin and Orbital Magnetic Moments (Angew. Chem. Int. Ed. 44/2019)

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Back Cover: [UF₆]²⁻: A Molecular Hexafluorido Actinide(IV) Complex with Compensating Spin and Orbital Magnetic Moments (Angew. Chem. Int. Ed. 44/2019)