Initial Results on the Composition of Fingerprints and its Evolution as a Functionof Time by GC/MS Analysis
Céline Weyermann Ph.D.
Institut de Police Scientifique, Université de Lausanne, Bâtiment Batochime, CH-1015 Lausanne, Switzerland.
Search for more papers by this authorClaude Roux Ph.D.
Centre for Forensic Science, Department of Chemistry, University of Technology, PO Box 123, Broadway, NSW—2007 Sydney, Australia.
Search for more papers by this authorChristophe Champod Ph.D.
Institut de Police Scientifique, Université de Lausanne, Bâtiment Batochime, CH-1015 Lausanne, Switzerland.
Search for more papers by this authorCéline Weyermann Ph.D.
Institut de Police Scientifique, Université de Lausanne, Bâtiment Batochime, CH-1015 Lausanne, Switzerland.
Search for more papers by this authorClaude Roux Ph.D.
Centre for Forensic Science, Department of Chemistry, University of Technology, PO Box 123, Broadway, NSW—2007 Sydney, Australia.
Search for more papers by this authorChristophe Champod Ph.D.
Institut de Police Scientifique, Université de Lausanne, Bâtiment Batochime, CH-1015 Lausanne, Switzerland.
Search for more papers by this authorAbstract
Abstract: Determining the time since deposition of fingermarks may prove necessary to assess their relevance to criminal investigations. The crucial factor is the initial composition of fingermarks, because it represents the starting point of any aging model. This study mainly aimed to characterize the initial composition of fingerprints, which show a high variability between donors (inter-variability), but also to investigate the variations among fingerprints from the same donor (intra-variability). Solutions to reduce this initial variability using squalene and cholesterol as target compounds are proposed and should be further investigated. The influence of substrates was also evaluated, and the initial composition was observed to be larger on porous surface than nonporous surfaces. Preliminary aging of fingerprints over 30 days was finally studied on a porous and a nonporous substrate to evaluate the potential for dating of fingermarks. Squalene was observed to decrease in a faster rate on a nonporous substrate.
References
- 1
Becue A,
Champod C,
Margot P.
Fingermarks, bitemarks and other impressions—a review. 15th Interpol Forensic Symposium; 2007 Oct 23–26; Lyon, France. In: Daeid NN,
Houck M, editors. Interpol’s forensic science review. New York, NY: CRC Press, Taylor and Francis LLC, 2010; 695–778.
10.1201/EBK1439826584-c16 Google Scholar
- 2 Champod C, Lennard C, Margot P, Stoilovic M. Fingerprints and other ridge skin impressions. In: J Robertson, editor. International forensic science and investigation series. Boca Raton, FL: CRC Press LLC, 2004; 106–11.
- 3 Wertheim K. Fingerprint age determination: is there any hope? J Forensic Identif 2003; 53(1): 42–9.
- 4 Knowles AM. Aspects of physicochemical methods for the detection of latent fingerprints. J Phys E: Scientific Instruments 1978; 11: 713–21.
- 5 Haahti E. Major lipids constituents of human skin surface with special reference to gas chromatographic methods. Scand J Clin Lab Invest 1961; 13(4): 1–108.
- 6 Kellum RE. Human sebaceous gland lipids. Analysis by thin-layer chromatography. Arch Derm 1967; 92(2): 218–20.
- 7 Stewart ME, Steele WA, Downing DT. Changes in the relative amounts of endogenous and exogenous fatty acids in sebaceous lipids during early adolescence. J Invest Dermatol 1989; 92: 371–8.
- 8 Takemura T, Wertz PW, Sato K. Free fatty acids and sterols in human ecrine sweat. Br J Dermatol 1989; 120: 43–7.
- 9 Fuchs E. Epidermal differentiation—the bare essentials. J Cell Biol 1990; 111(6): 2807–14.
- 10 Zhang ZM, Cai JJ, Ruan GH, Li GK. The study of fingerprint characteristics of the emanations from human arm skin using the original sampling system by SPME-GC/MS. J Chromatol 2007; B822(1–2): 244–52.
- 11 Olsen RD. The chemical composition of palmar sweat. Fingerprint Identification Magazine 1972; 53(10): 3–23.
- 12 Olsen RD. The chemical composition of sweat. In: Lentner C, editor. Geigy scientific tables. Volume I: Units of measurement, body fluids, composition of the body, nutrition, 8th rev. edn. West Caldwell, NJ: Ciba-Geigy Limited, 1981; 108–12.
- 13
Mong GM,
Petersen CE,
Clauss TRW.
Advanced fingerprint analysis project final report—fingerprint constituents. Richland, WA: Pacific Northwest National Laboratory, 99352, Report PNNL-13019, 1999.
10.2172/14172 Google Scholar
- 14
Ramotowski RS.
Composition of latent print residues. In: HC Lee,
RE Gaensslen, editors. Advances in fingerprint technology, 2nd edn. Boca Raton, FL: CRC Press, 2001; 63–104.
10.1201/9781420041347.ch3 Google Scholar
- 15 Hamilton PB. Amino-acids on hands. Nature 1965; 205(4968): 284–5.
- 16 Drapel V, Becue A, Champod C, Margot P. Proteins identification in latent fingermark residues. Forensic Sci Int 2009; 184: 47–53.
- 17 Buchanan MV, Asano K, Bohanan A. Chemical characterization of fingerprints from adults and children. SPIE 1997; 2941: 89–95.
- 18 Jacobsen E, Billings J, Frantz R, Kinney C, Stewart M, Downing D. Age-related changes in sebaceous wax ester secretion rates in men and women. J Invest Dermatol 1985; 84: 483–5.
- 19 Hemmila A, McGill J, Ritter D. Fourier transform infrared reflectance spectra of latent fingerprints: a biometric gauge for the age of an individual. J Forensic Sci 2008; 53(2): 1–8.
- 20 Asano KG, Bayne CK, Horsman K, Buchanan MV. Chemical composition of fingerprints for gender determination. J Forensic Sci 2002; 47: 805–7.
- 21 Archer NE, Charles Y, Elliot JA, Jickells S. Changes in the lipid composition of latent fingerprint residue with time after deposition on a surface. Forensic Sci Int 2005; 154: 224–39.
- 22 Thomas GL. The physics of fingerprints and their detection. J Phys E: Scientific Instruments 1978; 11: 722–31.
- 23 Bobev K. Fingerprints and factors affecting their conditions. J Forensic Identif 1995; 45: 176–83.
- 24 Holyst B. Kriminalistische abschätzung des spurenalters bei fingerpapillarlinien. Arch Kriminol 1978; 179: 94–103.
- 25 Almog J, Azoury M, Elmaliah Y, Berenstein L, Zaban A. Fingerprint’s third dimension: the depth and shape of fingerprints penetration into paper—a cross examination by fluorescence microscopy. J Forensic Sci 2004; 49(5): 981–5.
- 26 Almog J, Sasson Y, Anati A. Chemical reagents for the development of latent fingerprint. II: controlled addition of water vapor to iodine fumes—a solution to the aging problem. J Forensic Sci 1979; 24(2): 431–6.
- 27 Jones N, Mansour D, Stoilovic M, Lennard C, Roux C. The influence of polymer type, print donor and age on the quality of fingerprints developed on plastic substrates using vacuum metal deposition. Forensic Sci Int 2001; 124: 167–77.
- 28 Richmond-Aylor A, Bell S, Callery P, Morris K. Thermal degradation analysis of amino acids in fingerprint residue by pyrolysis GC-MS to develop new latent fingerprint developing reagents. J Forensic Sci 2007; 52(2): 380–2.
- 29 Ramotowski RS, Regen EM. The effect of electron beam irradiation on forensic evidence. 1. Latent print recovery on porous and non-porous surfaces. J Forensic Sci 2005; 50(2): 298–306.
- 30 Colella M, Parkinson A, Evans T, Lennard C, Roux C. The recovery of latent fingermarks from evidence exposed to ionizing radiation. J Forensic Sci 2009; 54(2): 1–8.
- 31 Hoile R, Walsh SJ, Roux C. Bioterrorism: processing contaminated evidence, the effects of formaldehyde gas on the recovery of latent fingermarks. J Forensic Sci 2007; 52(5): 1097–102.
- 32 Baniuk K. Determination of age of fingerprints. Forensic Sci Int 1990; 2: 133–7.
- 33 Schwabenland JF. Case report—determining the evaporation rate of latent impressions on the exterior surfaces of aluminium beverage cans. J Forensic Identif 1992; 42(2): 84–90.
- 34 McRoberts AL, Kuhn KE. A review of the case report—determining the evaporation rate of latent impressions on the exterior surfaces of aluminium beverage cans. J Forensic Identif 1992; 42(3): 213–8.
- 35 Midkiff CR. Lifetime of a latent print. How long? Can you tell? J Forensic Identif 1993; 43(4): 386–92.
- 36 Greenlees D. Age determination—case report. Fingerprint World 1994; 20(76): 50–2.
- 37 Duff JM, Menzel ER. Laser-assisted thin-layer chromatography and luminescence of fingerprints: an approach to fingerprint age determination. J Forensic Sci 1978; 23(1): 129–34.
- 38 Menzel ER. Fingerprint age determination by fluorescence. J Forensic Sci 1992; 37(5): 1212–3.
- 39 Jacquat A. Evolution des substances grasses des empreintes digitales au cours du temps: analyse par TLC et GC-MS [Master project]. Lausanne, Switzerland: Institut de Police Scientifique, Lausanne University, 1999.
- 40 Mountfort KA, Bronstein H, Archer N, Jickells SM. Identification of oxidation products of squalene in solution and in latent fingerprints by ESI-MS and LC/APCI-MS. Anal Chem 2007; 79: 2650–7.