Volume 81, Issue 2 pp. 164-167
opinions
Open Access

The chemical theory of valence

Ian David Brown

Corresponding Author

Ian David Brown

McMaster University, Brockhouse Institute for Materials Research, Hamilton, Ontario, L8S 4M1 Canada

Ian David Brown, e-mail: [email protected]Search for more papers by this author
First published: 12 February 2025

Abstract

Relaxing the restriction that valence can only adopt integer values removes the distinction between ionic and covalent bonds, resulting in a simple and powerful valence theory using the concept of the bonding strength of an element, defined as the ratio of its atomic valence to its average coordination number. Bonding strength, closely related to electronegativity, determines which atoms form stable bonds and the chemical properties of the resulting compounds of both organic and inorganic compounds.

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