Volume 60, Issue 5 pp. m705-m707

(Ethyl­enedi­amine-κ2N)(triethyl­enetetr­amine-κ4N)­nickel hexa­fluoro­germanate

Guo-Ming Wang

Guo-Ming Wang

Coordination and Hydro­thermal Chemistry Group, State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, People's Republic of China

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Yan-Qiong Sun

Yan-Qiong Sun

Coordination and Hydro­thermal Chemistry Group, State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, People's Republic of China

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Guo-Yu Yang

Guo-Yu Yang

Coordination and Hydro­thermal Chemistry Group, State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, People's Republic of China

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First published: 14 May 2004
Citations: 1
Guo-Yu Yang, e-mail: [email protected]

Abstract

The title compound, [Ni(en)(TETA)][GeF6] or [Ni(C2H8N2)(C6H18N4)][GeF6], was synthesized under mild solvothermal conditions in the presence of triethyl­enetetr­amine (TETA) as a base. It is a new salt composed of [GeF6]2− anions and [Ni(en)(TETA)]2+ cations. The ions are linked together by hydrogen bonding between F atoms and N—H groups. The complex cation and anion lie on twofold axes of the space group Pccn.

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