Volume 60, Issue 5 pp. m606-m608

Ethanol­(ethoxy)[3-methoxy­salicyl­aldehyde (4-methoxy­benzoyl)­hydrazonato-κ3O,N,O′]­oxovanadium(V)

First published: 14 May 2004
Citations: 1
Shan Gao, e-mail: [email protected]

Abstract

The six-coordinated VV atom in the title complex, [VOL(OCH2CH3)(CH3CH2OH)] [H2L = 3-methoxy­salicyl­aldehyde (4-methoxy­benzoyl)­hydrazone] or [VO(C2H5O)(C16H14N2O4)(C2H6O)], displays a distorted octahedral VO(ONO)(O)(O) coordination. The equatorial plane is defined by one N and two O atoms of the tridentate hydrazone ligand and the ethoxy O atom, while the axial oxo group is trans to the ethanol O atom. Adjacent mol­ecules are linked by intermolecular hydrogen bonds into a chain structure along the c axis.

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