Volume 60, Issue 5 pp. m593-m595

trans-Bis­(ethyl­enedi­amine)­bis(p-nitro­benzoxasulfamato)copper(II)

First published: 14 May 2004
Veysel T. Yilmaz, e-mail: [email protected]

Abstract

The structure of trans-[Cu(nbs)2(en)2] [nbs is the p-nitro­benzoxasulfamate anion (C6H3N2O5S) and en is ethyl­enedi­amine, C2H8N2] consists of neutral mol­ecules. The Cu2+ ion occupies an inversion centre and exhibits an elongated distorted octahedral geometry, with two monodentate nbs anions and two bidentate en ligands. Both nbs ligands are O-coordinated via an O atom of the nitro group. The crystal structure is stabilized by hydrogen bonds and weak aromatic π–π stacking interactions between the benzene rings of nbs ligands, forming a three-dimensional network.

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