Volume 60, Issue 5 pp. m574-m576

Chloro­bis(1,10-phenanthroline)copper(II) chloride methanol solvate 4.5-hydrate

Liping Lu

Liping Lu

Institute of Molecular Science, Chemical Biology and Molecular Engineering Laboratory of Education Ministry, Shanxi University, Taiyuan, Shanxi 030006, People's Republic of China

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Shidong Qin

Shidong Qin

Institute of Molecular Science, Chemical Biology and Molecular Engineering Laboratory of Education Ministry, Shanxi University, Taiyuan, Shanxi 030006, People's Republic of China

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Pin Yang

Pin Yang

Institute of Molecular Science, Chemical Biology and Molecular Engineering Laboratory of Education Ministry, Shanxi University, Taiyuan, Shanxi 030006, People's Republic of China

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Miaoli Zhu

Miaoli Zhu

Institute of Molecular Science, Chemical Biology and Molecular Engineering Laboratory of Education Ministry, Shanxi University, Taiyuan, Shanxi 030006, People's Republic of China

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First published: 14 May 2004
Citations: 2
Miaoli Zhu, e-mail: [email protected]

Abstract

In the title compound, [CuCl(C12H8N2)2]Cl·CH3OH·4.5H2O, the coordination geometry around the Cu atom is that of a trigonal bipyramid, with the central Cu atom bound to one Cl atom and four N atoms of the two phenanthroline ligands. The dihedral angle between the two phenanthroline planes is 49.6 (1)°; the dihedral angles between these planes and the equatorial plane of the trigonal bipyramid are 79.2 (1) and 88.4 (1)°.

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