Volume 58, Issue 11 pp. m628-m630

Poly­[[hexaacetatodiethano­ltrimagnesium(II)] diethanol solvate], a polymeric acetate-bridged magnesium chain structure

Andrew L. Hector

Andrew L. Hector

Department of Chemistry, University of Southampton, Highfield, Southampton SO17 1BJ, England

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Thomas A. Mayer

Thomas A. Mayer

Department of Chemistry, University of Southampton, Highfield, Southampton SO17 1BJ, England

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First published: 29 July 2004
Citations: 2
Andrew L. Hector, e-mail: [email protected]

Abstract

The title compound, [Mg3(C2H3O2)6(C2H6O)2]·2C2H6O, contains infinite chains of magnesium ions bridged by acetate ligands in three different coordination modes. There are two independent MgII ions in the asymmetric unit, and one lies on a twofold axis. The coordination geometry around each Mg ion is distorted octahedral.

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